MarvinSketch : Drawing link nodes

You can draw link nodes using the popup menu in two ways:

  1. Right-click on the atom to bring up the popup menu.
  2. Select the required repetition number from the Link node submenu. Marvin finds out the outer (non-repeating) bonds for you.

 

  1. Select the atom you would like to be the link node and two neighboring bonds for outer (non-repeating) bonds.
  2. Right-click anywhere on the canvas to bring up the popup menu.
  3. Select the required repetition number from the Link node submenu.


If it is not possible to create a link node for the specified configuration (for example at ring fusions) an error message is thrown.

Outer (non-repeating) bonds will be denoted by brackets crossing them, and the repetition numbers will be put on the atom.

All portion of the molecule connected to the link atom through non-outer bonds are supposed to repeat together with the atom.

See examples below.

Molecule with link node Meaning

To edit a link node repetition number or change outer bonds, repeat the drawing steps above.

To make a link atom ordinary atom again, select Off from the Link node submenu.